Decane is one of the components of gasoline petrol. Start studying gcse chemistry hydrocarbons, combustion. Mar 15, 2011 decane is cracked to give octane and ethene. In a shoe sole factory, the atmospheric concentration of decane was 70 fgm3 in the vulcanization. Octane and isooctane are structural isomers with the. Sep 06, 2015 5 cetanec 16 h34 can be cracked to produce hexane, buteneand ethene.
The equation below shows the cracking of a hydrocarbon compound into two different compounds, a and b. Nonane could also be split into two molecules of ethene and one molecule of ethane. In this reaction, decane decomposes into octane and ethene. Hexane c 6 h 14 with six carbon atoms in the chain. As level gce chemistry a specimen assessment material unit. Propane and butane are gases at standard temperature and pressure and are used commonly in lighters. These hydrocarbons can be cracked by strong heating.
Alkanes alkanes are saturated hydrocarbons contain single. In petrochemistry, petroleum geology and organic chemistry, cracking is the process whereby complex organic molecules such as kerogens or longchain hydrocarbons are broken down into simpler molecules such as light hydrocarbons, by the breaking of. This is achieved by heating the hydrocarbon molecules and passing the hydrocarbon gases over a catalyst france, 2008. There are two good economic reasons for cracking oil fractions i there isn. What is the balanced chemical equation for the combustion.
So my conclusion is that it would be a waste of time to try to use decane. Cracking allows large hydrocarbon molecules to be broken down into smaller, more useful. Jun 10, 2014 for example, decane an alkane with 10 carbons can be cracked to produce octane and ethene. Decane is an alkane hydrocarbon with the chemical formula c 10 h 22. The reaction of bromine with ethane is similar to that of. The following equation represents the cracking of decane to produce octane and ethene. The alkanes range in complexity from the simplest case of methane. Alkanes are hydrocarbons that contain only single bonds. Prevent entry into waterways, sewers, basements or confined areas. I used the molar mass of octane and decane to convert these to kg used for that amount of energy. In organic chemistry, an alkane, or paraffin a historical name that also has other meanings, is an acyclic saturated hydrocarbon. Jun 05, 2014 i took octane and balanced the equation and found its change in enthalpy during combustion, then i found the change in enthalpy of decane the same way. The phases of alkane at room temperature vary as the numbers of carbons are increase.
The cracking products, such as ethene, propene, buta1,3diene and c4. Crude oil and hydrocarbons essay 1123 words bartleby. Organic chemistryalkanespropane thru decane wikibooks. All these types of fuel are combustable, they create fire and heat. Heptane c 7 h 16 with seven carbon atoms in the chain. Thus the use of catalytic cracking plays a great role in the oil industry. Oil is heated to around 370 degrees and pumped into the fractional distillation tower where it is vaporized as the vaporized oil rises it cools and condenses at the top as it becomes more solidified heavy fractions long chained hydrocarbons are found near the bottom as they have higher boiling points. Gcse chemistry what is the chemistry of the cracking of. Q3c some fractions from crude oil contain large hydrocarbon molecules. Measurements of airborne decane have been taken in several industries. But, i think that means that decane has more energy per mol. The cracking products, such as ethene, propene, buta1,3diene and c 4 alkenes, are used to make many important chemicals. Cracking oil fractions reaction conditions products equations. Others such as branched and cyclic alkanes are added to the gasoline fraction obtained from the distillation of crude oil to enhance the octane rating.
These smaller hydrocarbons are then used as petrol iso octane or in the manufacture of plastics ethene. Justify the necessity of cracking and describe the purpose in your answer you may include chemical. A decane molecule is split into two smaller molecules. These molecules can be cracked to produce smaller, more useful molecules. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in which all the carboncarbon bonds are single. Long chain alkanes, such as nonane, are cracked into shorter chain alkanes and alkenes. Decane belongs to a very large organic family called alkanes. As the carbon number is increased, the phases change solid liquid gas. Structure, properties, spectra, suppliers and links for.
This is achieved by using high pressures and temperatures without a catalyst, or lower temperatures and pressures in the presence of a catalyst. Write a balanced symbol equation with state symbols for this. The ethene and propene are important materials for making plastics or producing. One of those isomeres, the isooctane 2,2,4trimetylpentane is especially important, because its octane rating is by definition 100.
Construct an equation to show the cracking of dodecane to. Animals showed signs of dyspnea, tachypnea, and cyanosis. If ndecane is released to the environment, it will be broken down in air. Dodecane c12h26 from crude oil is cracked to produce ethene c2h4. Thus, the homologous series of alkanes continues with pentane, hexane, heptane, octane, nonane, decane, and so on. Cracking is used to convert long alkanes into shorter, more useful hydrocarbons. Although 75 structural isomers are possible for decane, the term usually refers to the normal decane n decane, with the formula ch 3 ch 2 8 ch 3. The balanced equition for complete burning of dodecane is. Decane is an alkane hydrocarbon with the chemical formula ch3ch28ch3. Remembering that there must be one bond per hydrogen and four bonds per carbon, one can see that for the three simplest alkanes, there is only one configuration, or molecular structure that can exist, as shown in figure 37. Pentane c 5 h 12 with five carbon atoms in the chain.
Two of the liquid forms of hydrocarbons naphtha and kerosene are further broken or cracked by catalysts into smaller hydrocarbons. The octane is one of the molecules found in petrol gasoline. For example, decane an alkane with 10 carbons can be cracked to produce octane and ethene. Dodecane, c12h26, can be cracked into ethene and a straight chain alkane such that the molar ratio ethene. Some of the smaller hydrocarbons formed by cracking are used as fuels eg large chains are often cracked to form octane for petrol, which is in high demand, and the alkenes are used to make. Cracking is conducted at high temperatures, by two processes. Write a word equation for the cracking of decane but this time make something different 4b. A fuel is any material that can react with oxygen to release energy from a potential form into a usable form. In rats exposed by inhalation decane caused some limited, but statistically significant neurobehavioral effects at 5 gcu m, with no effects at 1.
Dodecane, c 12 h26, can be cracked into ethene and a straight chain alkane such that the molar ratio ethene. Deduce the molecular formula of x and write the equation for the. Butane c 4 h 10 with four carbon atoms in the chain. Thermal decomposition one of the products of cracking is pentane.
It needs to be separated into different fractions to be useful. What is the balanced equation for the complete combustion of. The reaction of decane with heat and a catalyst to produce pentane, propene and ethene is an example of what. Cracking of hydrocarbons involves thermal decomposition. This means that large hydrocarbon molecules break into. These smaller hydrocarbons are then used as petrol isooctane or in the manufacture of plastics ethene. State why high temperatures are necessary for cracking reactions to occur. The suffixis on the first four are from an obscure system but you should be familiar with the rest. Cracking of petroleum fractions was first achieved by heating. A vaporsuppressing foam may be used to reduce vapors. Learn vocabulary, terms, and more with flashcards, games, and other study tools. Original post by thefootyking19 can someone help me with this question please. Decane is a hydrocarbon that has 10 carbon and 22 hydrogen atoms covalently bonded to one another.
For example, hexane can be cracked to form butane and ethene. Molecular formulae and names of 6 to 10 carbon alkane. Justify the necessity of cracking and describe the purpose in your answer you may include chemical equations and diagrams. Alkanes crude oil, hydrocarbons and alkanes bbc bitesize. There is a greater demand for smaller hydrocarbons than larger ones. Like other alkanes, it is nonpolar and therefore will not dissolve in polar liquids such as water. Just remember, in a cracking equation, the reactant is a long alkane and the two products are smaller alkane and alkene molecules.
Write a balanced equation for the cracking of nonane into heptane and ethene. Production of ethylene production of materials youtube. It will move into air from moist soil and water surfaces. Cracking oil and cracking gcse chemistry single science. Thermal cracking involves the breaking of alkanes through the use of heat. Petrol and other fuels are produced from it using fractional distillation. For example, decane can be cracked to produce octane used in petrol and ethene used in the manufacturing of plastics. Predict the molecular formula of an alkane with carbon atoms total 1 mark 3. Write a balanced symbol equation for this reaction. Decane can be cracked to produce octane and ethene. Since the molar mass of decane is higher than octane i found that you need less octane in kg to make this amount of energy, by quite a bit i might add. Smaller molecules such as octane used in motor fuel and ethene used for the manufacture of plastic are made from cracking. Propane c 3 h 8 with three carbon atoms in the chain.
Octane has many structural isomers that differ by the amount and location of branching in the carbon chain. Write an equation to show how one molecule of cetanecan be cracked to form hexane, buteneand ethene. Crude oil is a mixture of hydrocarbons and is separated into small groups called. Generally, alkane with 4 carbons or less are gas at room temperature. Some foods contain ndecane naturally but in very low amounts. Cracking is the name given to breaking up large hydrocarbon molecules into smaller and. Apr 23, 20 decane is cracked to give octane and ethene. Cracking is the name given to breaking up large hydrocarbon molecules into smaller and more useful bits.
Octane is an organic chemical, specifically an alkane, with formula c8h18. Decane, all isomers page 4 table 3 chemical and physical data parameter ndecane reference molecular formula c 10 h 22 hsdb chemical structure chemspider cas registry number 124185 hsdb molecular weight 142. The octane molecule chemical and physical properties. C t1l c long chain alkanes, such as nonane, can be cracked into shorter chain alkanes and alkenes. Cracking is a thermal decomposition process by which large alkane hydrocarbon molecules are broken down by passing them over a heated catalyst at high pressure. Molecular formula and displayed formulae of octane. While decane is not a very useful substance, octane is a component of gasoline and ethene is used to make plastic. Cracking and alkenes crude oil, hydrocarbons and alkanes aqa. Absorb or cover with dry earth, sand or other noncombustible material and transfer to containers. Rewrite your word equation as a balanced symbol equation 5. The octane rating is on a scale where heptane is given an arbitary score of 0 and 2,2.
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